A few recognizable players there. Ben Amos and Dan Gore continuing the Man United links I noticed last season with Gore and James Wilson.
Ryan Croasdale and Rico Richards, I had them both in the early stages of my Stockport save, the former as captain and the latter on loan.
George Byers I've had in a previous save some years ago. I believe it was whilst I was playing in Scotland with St. Mirren. And Ronan Curtis is one I've scouted so many times due to amazing numbers in pace, stamina etc. Always looked like a perfect fit for me, but somehow the timing has never been right for me to look his way.
Nathan Smith is not a player I'm familiar with, but 345 for the Valiants must make him a club legend there. Not far from the top 10 all time appearance list, as far as I can tell.
List of Port Vale all-time appearances - onevalefan.co.uk
Edit: Just a heads up. According to transfermarkt - Nathan Smith - Stats 24/25 | Transfermarkt - Smith had 401 appearances for Port Vale prior to this season.