Like cooking, there are some skills that I too like to max out. Now, this is not the case for every sim, but only a certain type of sim, such as the one I'm playing now. The sim I'm playing now started out as human and has an LW wish to get to the top of the Law Enforcement Career. She basically loves to learn as much as she can. As a result, she found a way to become a witch. With this type of sim, these are the skills that I love to max out;
Alchemy
Cooking
Gardening - well at least up to 7
Spell Casting (hidden)
Science - this way she can clone the creatures instead of killing them for her potions
If I'm just playing your regular everyday sim then it would only be
Cooking, and Gardening They kind of go hand in hand.