Yes, happened to me. I mentioned it in the Walkthrough thread: http://forum.ea.com/eaforum/posts/list/10409502.page
He may be dressing up for his hero prep task before we officially own the skin, meaning it's more like a sneak peek than a glitch?
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Wow, I just read yours. Lol neither of us was keen enough to use him on a task before we erased the skin.
But all the tasks for the skin were available.
When the two come out of the duel task a second time is he still Longshot? I guess i'll find out in a few hours.
Sadly, the visible tasks are locked so I couldn't start those.
Gummy Joe and Skinner ended their task (a second time) and Skinner was in Longshot mode again, as seen in the screenshots below. I then successfully sent him on his 60 minute task.
Since Part 4 of the quest doesn't end until you collect all the Act 3 final pieces, I guess you can keep sending Joe and Skinner on their duel tasks if you really want to fiddle with Longshot. But you'll have to wait to get him officially before you start the visible tasks. And if you scroll to a different Skinner skin then you won't be able to go back to Longshot (until you end the duel task again).