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There was no save folder created in my documents.
The saves were located in the game folder which was something like
G:\Orgin Games\Bioware\Mass Effect 2\Binaries\(weird backwards "N" character)(Chinese character)\Saves
I tried manually copying the character folder to the standard folder c\users\ryanh\Documents\Bioware\Mass Effect 2\Saves
And still doesn't work?
Odd location for your ME2 save.
I have my Origin games install to the G-drive as well. My official documents folder is on the D-drive. I've gone to another PC since I played ME2, but did copy the file structure over and it does import to ME3. The relevant info:
ME2 save folder:
D:\[my login name]\Documents\BioWare\Mass Effect 2\Save (no "s" at the end of "Save")
If that still doesn't work, maybe start a new ME3 game, and see where it saves that one. Then go back up through that structure and make your Mass Effect 2 save structure there?