@Neo_Novalis I don't know about PS4 to PS5, but X One to Series X your team does transfer over. You can switch between both versions as well and your team will be upgraded...for example you buy/get a player on the Series X, it will be on the X One version as well, or vice versus. Now if you start H2H on one version, you have to complete that season on whatever gen you started it on.
What he is asking though is where a specific formation of the Saints playbook is located on the PS5, which I can't answer. A. I don't run the Saints playbook, and B. I don't have access to my account.