@laheehamzi1221 The only way the game itself could turn two Sims into siblings is if during the changes you make, you make them both children of the same Sim. And nothing the game itself does can revert to an earlier version of the relationship; that can happen only because of changes you make to households.
Nothing you do in the Library affects saves. The only way Library Sims end up in your game is if you put them there or if you use a mod that does that.
I suggest this, as both effective and giving you peace of mind:
- Move one Sim out into their own household
- Save each household to your Library as a separate, single-Sim household.
- Select "New"
- Load the two single-Sim households into your game. They will have no relationship to each other
- Merge the households through the Manage Households menu
- In CAS, make them married.