Here are the tasks I've come up with..
Molloy (Character set: Oldies)
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1hr - Attempt a Heist (Museum of Natural History)
4hrs - Become the Cat Burglar (visual task stealing from houses)
8hrs - Catch up with friends (Springfield Retirement Castle)
12hrs - Steal the Worlds Largest Zirconia (visual task. Must have zirconia)
24hrs - Serve Time (Springfield State Prison)
Dr. Colossus (Character set: Villains)
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1hr - Attempt to kill Snowball II (outside dual task with Snowball II)
4hrs - Plan villainous deeds (Death Mountain)
8hrs - Use Colosso Boots (outside task)
12hrs - Go in for Questioning (Police Station)
24hrs - Serve Time (Springfield Penitentiary)
Gloria Jailbird (Character set: Civil Servants)
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1hr - Look for Snake (Snake's Hideout)
4hrs - Go Bowling (Barney's Bowlarama)
8hrs - Give Parking Tickets (outside task in cop uniform)
12hrs - File Paperwork (Police Station)
24hrs - Go on a date with Monty (outside dual task with Mr. Burns)
Snake's new permanent tasks
2hrs - Hide from the Cops (Snake's Hideout)
3hrs - Fix up Lil' Bandit (outside task. Must have Lil' Bandit)