@lushifii The Users folder isn't inside Documents, which is what's open in your screenshot. Instead, you need to click This PC, a little further down in the left panel. It's right under OneDrive - Personal.
When you click This PC (not any of the categories under it, just This PC itself), double-click the C drive, then you'll see the Users folder.
When I make this transition, with my folders, will the “X mark” on documents disappear? Would I still have to unsync documents completely with OneDrive?
@lushifii If you don't sign into your Microsoft account when creating the new Windows account, your Microsoft account won't be linked at all, so OneDrive will not be a part of the setup.
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