@GiardiniDiMarzo The better option is whichever one gives you the results you want. In general, I trust the Nvidia setting more than the in-game one, and the results I've heard from other players back that up. But there are times when the Nvidia setting doesn't apply correctly, for example with certain dual-GPU laptops, and a few players have reported bad results with it over the years. So try each one and see what you think.
It sometimes helps to set a Max Frame Rate in the Nvidia Control Panel as well, although it in theory shouldn't be necessary if you're enabling vertical sync in either location and only playing in fullscreen mode.
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