I love all my Sims I would say one of my favourites is Victoria VanHelsing who was once a mortal Vampire Hunter. Her clan, like most clans hunting down the Supernatural such as vampires, werewolves, demons, ghosts etc. hates anything that isn't human. She made the mistake of falling in love with a vampire and was able to hide the fact from her family until one day her beloved Dante turned her and she became that Traitor that is now marked for termination by every hunter and stalker clan hunting down the supernatural and things of an occult nature. THey murdered Dante while she was in the middle of her vows to him. The thing with most hunter clans is they intermarry amongst themselves and hate everything that isn't human. They will occasionally allow members of the families to marry another human outside the other families. I constantly update her changing her look throughout when I have her in-game. Now she works as a hunter for the King of Vampires, Cain. She is in charge of that group of vampires hunting down truly evil and rogue vampires. When I play her I have her start a club for Vampires that meets every 3rd weekend of the month. It's a support group for vampires. When I play her I have a specific game plan in mind. She has a debt of honour to one of the Vampire Families.
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My favourite premade Sims are Paolo Rocca who often ends up married to some guy by the time my Sim meets him. I also love Caleb Vatore who I usually have Victoria hook up with. There is Joaquin Le Chien who doesn't know how to dress most of the time and often looks strung out that I really like. I have some ... interesting mods and custom traits that have the strongest affect him, Jonny Zest, Caleb Vatore and Paolo. I like Mila too because she is a hard-working single mom.