I roll randomly for the aspiration when a child sim first becomes a teen, and I try to play whatever aspirations sims come with when they join my household. It's one of the things that helps make my sims feel different from one another. So I've played with most of them at this point except for the Vampire and Home Chef Hustle ones (just recently got those packs). Haven't done Villainous Valentine but it would be fun with the right character.
I dislike Eco Innovator because it's annoying dealing with the voting board tasks when you don't live in a neighborhood with a voting board (not impossible since you can put a board on your home lot using the debug menu, but annoying), plus the milestone with selling power or water is first and can take a long time and then after that you get the milestone about voting on NAPs, but by then all four NAPs are usually in place, so then you have to repeal one...
I get bored with the aspirations that are just about grinding a skill and producing the same kind of item over and over, like the writing and painting ones, but if I have them active for long enough on a sim who is a writer or painter, they get fulfilled eventually on their own without my having to bother much about them.