I made a family in CAS with two female Sims and two children. I set one of them to "can get others pregnant" and the other to "can get pregnant" so that I could make them have biological children.
When I looked back at the family in the Gallery, I realized one of them wasn't set as their mother, so I went to fix it in the relationship tab in CAS. When I tried to change the other Sim to be the child's mother, the first mother gets changed to just a household member. It won't let both Sims be listed as the children's parents at the same time.
It doesn't work with mods on or disabled, and I'm playing on PC. I also tested another family that's set up the exact same way with different Sims, and it works correctly. So for some reason, this seems to only be happening with this specific family.