deargrasiella When you say you checked ConfigOverride, do you mean you made sure it was empty or deleted everything inside? If not, please do so now.
If that doesn't or didn't help, please disable or uninstall LG Hub, which is crashing. Disabling may not be enough, so please uninstall it if disabling doesn't work.
If that doesn't help either, please please look for new errors in the Reliability Monitor. Hit Windows key-R and enter "perfmon /rel" without quotes, and you'll see a chart of errors and updates with a column for each day. Today is on the right.
Try to play again, then look for an error that happened at exactly the time of your most recent crash. If you find one, double-click it to see more details, then copy that info and paste it into a reply here. If you don't see a new error, check back in an hour or so—the Reliability Monitor doesn't always update right away.